I can tell you what I used. I picked up a spray can of black appliance enamel at either Wal-Mart or Lowes and it worked great. The trick is to spray a VERY thin first coat and wait for that to dry before spraying a second coat. It turned out nice. It was very shiny. Make sure the glass surface is absolutely clean and absolutely dry first. I did a final wipe down with plain water with a little vinegar in it and then dried it very well. I guess rubbing alcohol would work too but I didn't have any of that laying around.
I used masking tape and old newspapers to make sure that all of the surrounding glass was covered. And, of course, I did this outdoors on an empty, brand new tank.
One should be EXTREMELY wary of using paint on a tank that has inhabitants! In fact, one should be extremely wary of using paint anywhere near a tank that has inhabitants.



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