Diatoms need silica to grow, so I'd suspect your source water for that.
instead of carbon, I'd run chemi-pure elite. it has phosphate and silica medias added to it.
I'd also drop the trace elements to 25% of recommended dosage.
and either use up or get rid of the purple up and switch to good calcium and alkalinty supplements (I love oceans blend two part).
The oily film is built up proteins and a skimmer would deal with a lot of it. but without and overflow box/surface skimmer, it can be tough to totally eliminate it. drapping and dragging paper towels across it can help pick it up.
as a side note, it's also possible that the film is reducing spectrum and par to favor the diatom growth.



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