You can add a 10 gallon or larger refugium to your tank to hold various macro algaes for nutrient export, it's an excellent idea! The key is to make sure you are constantly prunning the macro algae to ensure you are actually exporting nutrients.
Can you use this with bio-balls? Sure you can but it is surely counter productive. You best bet would be to set up the refugium with the algae and after a good 3-4 week start on it, slowly start removing the bio-balls from your wet/dry.



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