ORP is only good as a relative test (i.e. watching for changes) and measures the amount of electrons available for oxidation reduction reactions. Yes, oxygen is a good electron donor, but other substances are also good electron donors and will also show high ORP. Sulfuric acid shows high ORP levels, for example. So a high ORP level does not ensure enough oxygen in solution.
If you are worried about your oxygen level, make sure your tank has good circulation and is open to air exchange. Many other things can cause hypoxia (low oxygen levels) in animals other than the lack of oxygen in the water. Gill parasites, for example, can prevent oxygen from being absorbed by the fish, which can result in a purple or blue coloration to the blood and gills.
Your gas exchange - including oxygen - should be just fine. (Since your alkalinity and pH are normal, there is adequate exchange of CO2, so O2 exchange should also be good.)
Unless you are doing scientific research, the O2 monitor is probably a waste of money (as is the O2 test). ORP is useful if you run an ozonizer - it makes sure you add enough to work without poisoning your tank. If you don't have an ozonizer, the ORP probe is also pretty useless.
Bottom line: your oxygen level is probably just fine (given your other tank readings). Your fish probably died of an illness that caused it not to be able to absorb enough oxygen (gill parasites).



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